Yes, you can use a 21 inch tube in the rear, though you'd do well to inflate it to full pressure (around 35psi) otherwise there's a very high risk of getting another puncture very quickly (compression puncture)
I've been plagued with punctures since fitting my TKC80's and have used a 21 tube several times now, still haven't figured why I was getting punctures as they were all compression type and all whilst on tarmac

, at the moment I'm guessing that running TKC's at low pressures of around 15psi is no good, the tyre walls do seem to be soft, so from now on I'm running 35psi